What does this jumper between clipping paths do?

Theoretically not much. If one set of diodes is forward biased, the other is reverse biased with or without the bridge. There is a little junction capacitance added, but it's on the order of 4pF for 1n4148 and 15pF for 1N4004.

Paul Cochran, creator of the original Timmy pedal claims there is a subtly audible difference. Did you end up breadboarding to see if you heard a difference? I don't hear one if I add/remove a jumper, but I'm in my 60s and my ears are kind of shot anyway.
The first place saw this was in a Timmy/Timmy clone schematic where it allowed use of a SPDT with open center position to provide 2 options:
1) open - 2 diodes in each direction
2) short out a diode pair for 1 diode in each direction
3) switch in a single diode in one direction for asymmetrical clipping.

Search "Timmy clone Super-Freq schematic" for a drawing. There is also a bit of discussion in the various DIY forums and PaulC participated at times.
 
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