When you drive an op amp beyond its output swing range, 0V to 9V for example, the output signal will start to clip. More gain = more clipping. Less supply voltage = earlier clipping. You bias to 1/2 VCC, 4.5V in this case, to ensure the output can swing symmetrically around this midpoint because it will maximize the available range and thus clean headroom. When you intentionally misbias the op amp, the output will swing asymmetrically, meaning one side of the output signal will hit the power rails sooner than the other and thus also clip sooner. This will create asymmetrical distortion.
You should be aware, op amp clipping is kind of an aquired taste and doesn't always sound very nice unless the circuit is really built around it. That's not going to change much by misbiasing the op amp either.